Structural, Spectroscopic and Molecular Characterization of an Asymmetric Schiff Base Compound


Doğan O. E., Poyraz E. B., Saracoglu H., Agar T., Yasa B., Dege N.

JOURNAL OF STRUCTURAL CHEMISTRY, vol.64, no.6, pp.1147-1163, 2023 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 64 Issue: 6
  • Publication Date: 2023
  • Doi Number: 10.1134/s0022476623060161
  • Journal Name: JOURNAL OF STRUCTURAL CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, INSPEC
  • Page Numbers: pp.1147-1163
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

2-((E)-((2-(((E)-2-hydroxy-3-methylbenzylidene)amino)benzyl)imino)methyl)-6-methylphenol, C23H22N2O2, was synthesized by the reaction between 2-hydroxy-3-methylbenzaldehyde, and 2-(aminomethyl)aniline in aqueous ethanol. X-ray diffraction analysis technique was used to reveal the structure. The crystal structure is monoclinic, space group P2(1)/c with parameters a = 4.6035(11) angstrom, b = 18.895(3) angstrom, c = 21.748(6) angstrom, beta = 100.23(4)degrees, V = 1794(16) angstrom(3), Z = 4. It was determined by the Hirshfeld surface study that intermolecular hydrogen bonds stabilized the complex structure. Structure verified by Fourier transform infrared spectra technique.