(E)-3-{[(2-Bromo-3-methylphenyl)imino]methyl)benzene-1,2-diol: crystal structure and Hirshfeld surface analysis

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Doğan O. E., DEGE N., Ağar E., Fritsky I. O.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, vol.75, pp.1930-1940, 2019 (ESCI) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 75
  • Publication Date: 2019
  • Doi Number: 10.1107/s2056989019015718
  • Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
  • Journal Indexes: Emerging Sources Citation Index (ESCI), Scopus
  • Page Numbers: pp.1930-1940
  • Keywords: crystal structure, Schiff base, O center dot center dot center dot O interaction, Hirshfeld surface analysis, hydrogen bonds, BENZYLIDENEANILINES, SCHIFF
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

The title compound, C14H12BrNO2, was synthesized by the condensation reaction of 2,3-dihydroxybenzaldehyde and 2-bromo-3-methylaniline. It crystallizes in the centrosymmetric triclinic space group P (1) over bar. The configuration about the C=N bond is E. The dihedral angle between the planes of the 5-(2-bromo-3-methylphenyl ring and the catechol ring is 2.80 (17)degrees. In the crystal, O-H center dot center dot center dot O hydrogen-bond interactions consolidate the crystal packing.