Diapuabis(1,10-phenanthroline)cobalt(II) diorotate 2.25-hydrate

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Copy For Citation

Bulut A., Icbudak H., YEŞİLEL O. Z., Olmez H., Buyukgungor O.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, vol.59, 2003 (SCI-Expanded)

• Publication Type: Article / Article
• Volume: 59
• Publication Date: 2003
• Doi Number: 10.1107/s1600536803017161
• Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED)
• Ondokuz Mayıs University Affiliated: No

Abstract

In the title compound, [Co(C12H8N2)(2)(H2O)(2)](C5H3N2O4)(2) .2.25H(2)O, the cobalt cation, located on a twofold axis, is coordinated by two symmetry-related aqua ligands together with a pair of symmetry-related bidentate phenanthroline ( phen) molecules, and exhibits a distorted octahedral coordination. The unique orotate anion in the asymmetric unit has a single negative charge. The coordinated water molecules link the orotate ions to the metal complex via O-H...O hydrogen bonds. Each uncoordinated water molecule is hydrogen bonded to orotate ions through O-H...O hydrogen bonds.