O,O-bis(2-tert-butylphenyl) chlorothiophosphonate

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Odabasoglu M., Buyukgungor O.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, vol.63, 2007 (SCI-Expanded)

• Publication Type: Article / Article
• Volume: 63
• Publication Date: 2007
• Doi Number: 10.1107/s1600536806055371
• Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED)
• Ondokuz Mayıs University Affiliated: No

Abstract

The title compound, C20H26ClO2PS, displays distorted tetrahedral geometry around the P atom, which lies on a crystallographic twofold axis. The S and Cl substituents on the P atom are disordered about the twofold axis. The internal angles in the aromatic rings vary significantly due to the steric influence of the tert-butyl groups. Weak intramolecular C-H center dot center dot center dot O hydrogen bonds generate two S( 6) motifs. The crystal structure is stabilized only by van der Waals interactions.