Synthesis and Structural Studies of 6-(2,5-Dimethyl-1H-pyrrol-1-yl)pyridin-2-amine

Sahin Z. S., KARABÖCEK S., Senses E., Karabocek E., Isik S.

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, vol.29, no.5, pp.720-725, 2010 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 29 Issue: 5
  • Publication Date: 2010
  • Journal Name: CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.720-725
  • Keywords: 2,6-diaminopyridine, Schiff bases, methylpyridine, pyrrol, SCHIFF-BASE LIGANDS, PAAL-KNORR REACTION, PYRROLE SYNTHESIS, COMPLEXES, COPPER(II), CHEMISTRY, ANALOGS
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

6-(2,5-Dimethyl-1H-pyrrol-1-yl)pyridin-2-amine (1) was synthesized and characterized by elemental analyses, (1)H-NMR and (13)C-NMR, FTIR, Uv-Vis, mass spectral studies and single-crystal X-ray diffraction. All data obtained from spectral studies support the structural properties of 1. Intermolecular N-H center dot center dot center dot N hydrogen bonds produce an R(2)(2)(8) ring. An extensive three-dimensional network formed by C-H center dot center dot center dot pi and N-H center dot center dot center dot pi-facial hydrogen bonds is responsible for the crystal stabilization. The combination of C H g interactions produces R(3)(3)(12), R(4)(3)(19) and R(4)(4)(20) rings.