Design and construction of six coordination polymers with imidazole-4,5-dicarboxylate ligand

ERER H., YEŞİLEL O. Z., ŞAHİN O., Buyukgungor O.

INORGANICA CHIMICA ACTA, vol.434, pp.14-23, 2015 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 434
  • Publication Date: 2015
  • Doi Number: 10.1016/j.ica.2015.05.003
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.14-23
  • Keywords: Coordination polymers, Imidazole-4,5-dicarboxylate complexes, Bis(imidazole) linkers, 1,2-Di(pyridin-4-yl)ethene complexes, METAL-ORGANIC FRAMEWORKS, CRYSTAL-STRUCTURES, TOPOLOGICAL DIVERSITY, STRUCTURAL DIVERSITY, SERIES, COMPLEXES, NETWORKS, TRICARBOXYLATE, ADSORPTION, SOLVENTS
  • Ondokuz Mayıs University Affiliated: Yes


Six new metal-organic frameworks based on a rigid multifunctional ligand imidazole 4,5-dicarboxylic acid (H(3)idc), namely, [Zn-3(mu(3)-idc)(mu(5)-idc)](n) (1), {[Zn-3(mu(3)-idc)(2)(H2O)(dpeten)](n)center dot 2H(2)O}(n) (2), [Zn(mu-Hidc)-( mu-obix)(0.5)](n) (3), [Zn-4(mu-Hidc)(4)(mu-mbix)(2)](n) (4), {[Cd-5(mu(5)-idc)(2)(mu(4)-Hidc)(2)(H2O)(2)]center dot 2H(2)O}(n) (5) and [Cd-2(mu(3)-Hidc)(2)(mu-obix)](n) (6) (H(3)idc = imidazole-4,5-dicarboxylic acid, obix = 1,2-bis(imidazol-1-yl-methyl)-benzene, mbix = 1,3-bis(imidazol-1-yl-methyl)-benzene and dpeten = 1,2-di(pyridin-4-yl)ethene), have been constructed under hydro(solvo)thermal conditions and structurally characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, powder X-ray diffraction (PXRD) and thermal analyses (TG, DTA, DSC) techniques. In these compounds, the ligand, H(3)idc, exhibits different coordination modes, constructing various architectures by bridging a variety of metal ions or polynuclear clusters. All of these coordination polymers exhibited intense fluorescent emissions in the solid state at room temperature. Furthermore, topological properties were studied. (C) 2015 Elsevier B.V. All rights reserved.