Bis(phenanthridinium) hexachloridoplatinate(IV) dimethyl sulfoxide disolvate

Karaca, Selvi; AKKURT, MEHMET; Safari, Nasser; Amani, Vahid; Bueyuekguengoer, Orhan; Abedi, Anita

doi:10.1107/s1600536809002736

Bis(phenanthridinium) hexachloridoplatinate(IV) dimethyl sulfoxide disolvate

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Karaca S., AKKURT M., Safari N., Amani V., Bueyuekguengoer O., Abedi A.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, vol.65, 2009 (SCI-Expanded)

Publication Type: Article / Article
Volume: 65
Publication Date: 2009
Doi Number: 10.1107/s1600536809002736
Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED)
Ondokuz Mayıs University Affiliated: Yes

Abstract

The asymmetric unit of the title compound, (C13H10N)(2)-[ PtCl6]center dot 2C(2)H(6)OS, contains one independent protonated phenanthridinium cation, half of a centrosymmetric [PtCl6](2-) anion and one dimethyl sulfoxide solvent molecule. Intramolecular N-H center dot center dot center dot O and intermolecular C-H center dot center dot center dot Cl hydrogen-bonding interactions seem to be effective in the stabilization of the structure.