Syntheses, crystal structures and spectroscopic properties of cyano-bridged two-dimensional coordination polymers with 3-methylpyridazine

Gor K., KÜRKÇÜOĞLU G. S., YEŞİLEL O. Z., Buyukgungor O.

INORGANICA CHIMICA ACTA, vol.414, pp.15-20, 2014 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 414
  • Publication Date: 2014
  • Doi Number: 10.1016/j.ica.2014.01.023
  • Journal Name: INORGANICA CHIMICA ACTA
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.15-20
  • Keywords: Cyano-bridged complex, 3-Methylpyridazine complex, Tetracyanonickelate( II) complex, Tetracyanopalladate( II) complex, Tetracyanoplatinate( II) complex, INFRARED-ABSORPTION SPECTRA, PRUSSIAN BLUE ANALOGS, MAGNETIC-PROPERTIES, THERMAL ANALYSES, VIBRATIONAL-SPECTRUM, IR-SPECTRA, COMPLEXES, ION, TRANSITION, CHEMISTRY
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

Six new two-dimensional heteropolynuclear complexes, [ M( 3- mpdz)(2)M(mu l- CN)(4)](n) ( M = Zn( II) or Cd( II); M0 = Ni( II), Pd( II) or Pt( II); 3- mpdz = 3-methylpyridazine) were synthesized and characterized by FT- IR, Raman spectroscopy, single crystal X- ray diffraction, thermal and elemental analyses techniques. The crystallographic analyses reveal that these complexes crystallize in the monoclinic system, space group C2/ m. The M0( II) ion is coordinated by four cyanide- carbon atoms in a square planar geometry and the M( II) ion exhibits a distorted octahedral coordination with two 3- mpdz ligands and four bridging cyano groups. In all the complexes, adjacent 2D layers are further extended into 3D supramolecular network through C- H tau interactions. Thermal stabilities and decomposition products of the complexes were investigated in the temperature range of 30- 700 circle C in air atmosphere.(C) 2014 Elsevier B. V. All rights reserved.