trans-Bis(nitrato-kappa O)tetrakis(1-vinyl-1H-imidazole-kappa N-3)copper(II)
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.68, 2012 (ESCI, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 68
- Basım Tarihi: 2012
- Doi Numarası: 10.1107/s1600536812030607
- Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
- Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
- Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
- Ondokuz Mayıs Üniversitesi Adresli: Evet
Özet
In the title compound, [Cu(NO3)(2)(C5H6N2)(4)], the Cu-II ion is located on an inversion centre. It features a Jahn-Teller-distorted octahedral coordination geometry, defined by four N atoms of four 1-vinylimidazole ligands in the equatorial plane and two nitrate O atoms in the axial positions. The nitrate anion is disordered over two sets of sites in a 0.801 (6): 0.199 (6) ratio. In the crystal, the complex molecules are linked by weak intermolecular C-H center dot center dot center dot O and C-H center dot center dot center dot pi interactions.