Crystal structure and DFT study of bis{(S)-2-[(2-hydroxybenzyl)amino]-4-methylpentanoato-kappa N-2,O}(1,10-phenanthroline-kappa N-2,N ')nickel(II)
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, vol.73, pp.1393-1406, 2017 (ESCI, Scopus)
- Publication Type: Article / Article
- Volume: 73
- Publication Date: 2017
- Doi Number: 10.1107/s2056989017012014
- Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
- Journal Indexes: Emerging Sources Citation Index (ESCI), Scopus
- Page Numbers: pp.1393-1406
- Keywords: crystal structure, nickel(II), phenanthroline, amine, leucine, salicylaldehyde, C-H center dot center dot center dot pi interactions, hydrogen bonding, BASIS-SETS, COMPLEXES, NICKEL, CLEAVAGE, ACID, DNA
- Open Archive Collection: AVESIS Open Access Collection
- Ondokuz Mayıs University Affiliated: Yes
Abstract
In the title compound, [Ni(C13H18NO3)(2)(C12H8N2)], the Ni-II cation shows a distorted octahedral coordination environment. It is formed by two N atoms from the phenanthroline ligand, as well as two N and two O atoms belonging to two 2-[(2-hydroxybenzyl)amino]-4-methylpentanoate ligands. Complex molecules are connected into layers propagating along the ab plane via hydrogen bonds formed by O atoms of carboxylate and phenoxide groups, which are further connected into a three-dimensional motif.