Crystal structure and DFT study of bis{(S)-2-[(2-hydroxybenzyl)amino]-4-methylpentanoato-kappa N-2,O}(1,10-phenanthroline-kappa N-2,N ')nickel(II)

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Faizi M. S. H., DEGE N., Malinkin S.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.73, ss.1393-1406, 2017 (ESCI) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 73
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1107/s2056989017012014
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
  • Sayfa Sayıları: ss.1393-1406
  • Anahtar Kelimeler: crystal structure, nickel(II), phenanthroline, amine, leucine, salicylaldehyde, C-H center dot center dot center dot pi interactions, hydrogen bonding, BASIS-SETS, COMPLEXES, NICKEL, CLEAVAGE, ACID, DNA
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

In the title compound, [Ni(C13H18NO3)(2)(C12H8N2)], the Ni-II cation shows a distorted octahedral coordination environment. It is formed by two N atoms from the phenanthroline ligand, as well as two N and two O atoms belonging to two 2-[(2-hydroxybenzyl)amino]-4-methylpentanoate ligands. Complex molecules are connected into layers propagating along the ab plane via hydrogen bonds formed by O atoms of carboxylate and phenoxide groups, which are further connected into a three-dimensional motif.