Synthesis, crystal structure, vibrational spectra and thermal property of the cyano-bridged hetero-nuclear polymeric complex [Cd(pea)(2)Ni(mu-CN)(4)](n)

KÜRKÇÜOĞLU G. S., YEŞİLEL O. Z., Cayli I., Buyukgungor O.

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, vol.224, no.10, pp.493-498, 2009 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 224 Issue: 10
  • Publication Date: 2009
  • Doi Number: 10.1524/zkri.2009.1176
  • Journal Name: ZEITSCHRIFT FUR KRISTALLOGRAPHIE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED)
  • Page Numbers: pp.493-498
  • Keywords: Cyano-bridged complex, Tetracyanonickelate(II), Phenylethylamine, Infrared and Raman spectra, Heteronuclear complex, Single crystal structure analysis, X-ray diffraction, IR-SPECTRUM, TETRACYANONICKELATE(II), SPECTROSCOPY, BENZENE, ION
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

The cyano-bridged heterometallic complex, [Cd(pea)(2)Ni(mu-CN)(4)](n), (1), (pea = 2-phenylethylamine), has been synthesized and characterized by single crystal X-ray diffraction analysis, vibrational (FT-IR and Raman) spectroscopy, elemental and thermal analyses. The crystallographic analysis reveals that the crystal structure of the complex consists of a corrugated two dimensional network, in which the coordination environment of the Cd(II) ion possesses a distorted octahedral geometry, whereas that of Ni(II) has a square planar geometry. The spectral features are consistent with pea coordination to the cadmium ion of the [Cd-Ni(mu-CN)(4)](n) layers as a monodentate ligand.