Synthesis and Crystal Structure of Nickel(II) and Zinc(II) Complexes with O-Propylxanthate and N, N, N′,N′-Tetramethylethylenediamine

Qadir A., DEGE N.

Journal of Structural Chemistry, cilt.60, sa.5, ss.810-814, 2019 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 60 Sayı: 5
  • Basım Tarihi: 2019
  • Doi Numarası: 10.1134/s0022476619050147
  • Dergi Adı: Journal of Structural Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.810-814
  • Anahtar Kelimeler: complex, synthesis, X-ray, xanthate, Zn(II)
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

The reaction of NiCl2·6H2O or Zn(CH3CO2)·2H2O with potassium O-propylxanthate (KS2COC3H7) and N, N, N′,N′-tetramethylethylenediamine (tmeda) affords monomeric complexes of the formula [M(S2COC3H7)2(tmeda)] (M = Ni(II) 1; Zn(II) 2). Both complexes are characterized by single crystal X-ray diffraction, elemental analysis, IR spectroscopy. Complexes 1 and 2 crystalize in monoclinic P21/c and I2/a space groups, respectively. Each metal center is ligated by four S atoms from xanthate ligands and two N atoms from tmeda in a distorted octahedral geometry.