Di-mu-iodido-bis{[(4-fluorobenzoylmethylene)triphenyl-lambda(5)-phosphorane]iodido-mercury(II)}

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AKKURT M., Karami K., Yalcin S. P., Buyukgungor O.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, vol.64, 2008 (SCI-Expanded)

• Publication Type: Article / Article
• Volume: 64
• Publication Date: 2008
• Doi Number: 10.1107/s1600536808008611
• Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED)
• Ondokuz Mayıs University Affiliated: Yes

Abstract

In the title complex, [Hg2I4(C26H20FOP)(2)], the Hg-II centre is four-coordinate with one short Hg-I bond [2.6895 (7) A], one Hg-C bond and two asymmetric bridging Hg-I bonds with distances of 2.7780 (8) and 3.2599 (8) A. The title molecule has a crystallographic inversion centre at the centroid of the four-membered ring formed by the two Hg atoms and two I atoms. The crystal packing is stabilized by C-H center dot center dot center dot O hydrogen bonds.