Polarographic and voltammetric behaviour of 2-hydroxy-3-methoxy-5-(2-propenyl) azobenzene
Analytical Letters, cilt.31, sa.2, ss.275-282, 1998 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 31 Sayı: 2
- Basım Tarihi: 1998
- Doi Numarası: 10.1080/00032719808002045
- Dergi Adı: Analytical Letters
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.275-282
- Anahtar Kelimeler: Azo compound, Polarography, Voltammetry
- Ondokuz Mayıs Üniversitesi Adresli: Evet
Özet
The polarographic reduction of 2-hydroxy-3-methoxy-5-(2-propenyl) azobenzene in Britton Robinson Buffer with pH range 3 and 12 at room temperature has been investigated in aqueous solution of ratio 1:1. Two straight lines were obtained from the Ep-pH plots for the compound. Using the pH dependence of the polarographic and voltammetric behaviour of the azo compound the pKa value was determined to be 10.70 ± 0.02 and 11.08 ± 0.02, respectively. An electrode reaction mechanism for the azo compound has been suggested. The determination limit has been found as 1 x 10-7 M.