Structural, Spectroscopic and Molecular Characterization of an Asymmetric Schiff Base Compound

Doğan O. E., Poyraz E. B., Saracoglu H., Agar T., Yasa B., Dege N.

JOURNAL OF STRUCTURAL CHEMISTRY, cilt.64, sa.6, ss.1147-1163, 2023 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 64 Sayı: 6
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1134/s0022476623060161
  • Dergi Adı: JOURNAL OF STRUCTURAL CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, INSPEC
  • Sayfa Sayıları: ss.1147-1163
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

2-((E)-((2-(((E)-2-hydroxy-3-methylbenzylidene)amino)benzyl)imino)methyl)-6-methylphenol, C23H22N2O2, was synthesized by the reaction between 2-hydroxy-3-methylbenzaldehyde, and 2-(aminomethyl)aniline in aqueous ethanol. X-ray diffraction analysis technique was used to reveal the structure. The crystal structure is monoclinic, space group P2(1)/c with parameters a = 4.6035(11) angstrom, b = 18.895(3) angstrom, c = 21.748(6) angstrom, beta = 100.23(4)degrees, V = 1794(16) angstrom(3), Z = 4. It was determined by the Hirshfeld surface study that intermolecular hydrogen bonds stabilized the complex structure. Structure verified by Fourier transform infrared spectra technique.