Structural, Spectroscopic and Molecular Characterization of an Asymmetric Schiff Base Compound
JOURNAL OF STRUCTURAL CHEMISTRY, cilt.64, sa.6, ss.1147-1163, 2023 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 64 Sayı: 6
- Basım Tarihi: 2023
- Doi Numarası: 10.1134/s0022476623060161
- Dergi Adı: JOURNAL OF STRUCTURAL CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, INSPEC
- Sayfa Sayıları: ss.1147-1163
- Ondokuz Mayıs Üniversitesi Adresli: Evet
Özet
2-((E)-((2-(((E)-2-hydroxy-3-methylbenzylidene)amino)benzyl)imino)methyl)-6-methylphenol, C23H22N2O2, was synthesized by the reaction between 2-hydroxy-3-methylbenzaldehyde, and 2-(aminomethyl)aniline in aqueous ethanol. X-ray diffraction analysis technique was used to reveal the structure. The crystal structure is monoclinic, space group P2(1)/c with parameters a = 4.6035(11) angstrom, b = 18.895(3) angstrom, c = 21.748(6) angstrom, beta = 100.23(4)degrees, V = 1794(16) angstrom(3), Z = 4. It was determined by the Hirshfeld surface study that intermolecular hydrogen bonds stabilized the complex structure. Structure verified by Fourier transform infrared spectra technique.