trans-rac-methyl 2-hexyl-1-oxo-3-(2-pyridyl)-1,2,3,4-tetrahydroisoquinoline-4-carboxylate

YILDIRIM, SEMA; AKKURT, MEHMET; Kandinska, Meglena; Bogdanov, Milen; Buyukgungor, Orhan

doi:10.1107/s1600536808029048

trans-rac-methyl 2-hexyl-1-oxo-3-(2-pyridyl)-1,2,3,4-tetrahydroisoquinoline-4-carboxylate

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YILDIRIM S., AKKURT M., Kandinska M. I., Bogdanov M. G., Buyukgungor O.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, vol.64, 2008 (SCI-Expanded)

Publication Type: Article / Article
Volume: 64
Publication Date: 2008
Doi Number: 10.1107/s1600536808029048
Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED)
Ondokuz Mayıs University Affiliated: Yes

Abstract

The title compound, C(22)H(26)N(2)O(3), was synthesized by esterification of trans-rac- 2-hexyl-1-oxo-3-(2-pyridyl)-1,2,3,4-tetrahydroisoquinoline-4-carboxylic acid in the presence of H(2)SO(4) in methanol. The dihedral angle between the benzene and pyridine rings is 84.46 (17)degrees. The piperidine ring adopts a screw-boat conformation. In the crystal, inversion dimers linked by two C-H center dot center dot center dot O bonds occur.