Crystal structure and Hirshfeld surface analysis of [2-(1H-benzimidazol-2-yl-kappa N-3)aniline-kappa N]dichloridozinc(II) N,N-dimethylformamide monosolvate
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, cilt.77, ss.491-499, 2021 (ESCI, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 77
- Basım Tarihi: 2021
- Doi Numarası: 10.1107/s2056989021003649
- Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
- Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
- Sayfa Sayıları: ss.491-499
- Anahtar Kelimeler: crystal structure, benzimidazole, aniline, bidentate ligand, heterocyclic, zinc(II) complex, LONE PAIR-PI, BIOLOGICAL EVALUATION, DERIVATIVES
- Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
- Ondokuz Mayıs Üniversitesi Adresli: Evet
Özet
The title compound, [ZnCl2(C13H11N3)]center dot C3H7NO, crystallized in the monoclinic crystal system in space group P2(1)/n. The asymmetric unit contains one neutral complex molecule, which consists of a zinc ion, a bidentate ligand, and two chlorido ligands with dimethylformamide monosolvate. The ligand has two moieties, a benzimidazole and an aniline group. The benzimidazole and aniline planes are not coplanar, subtending a dihedral angle of 18.24 (8)degrees. The Zn(II) ion shows distorted tetrahedral geometry, being coordinated by an imidazole N atom, the aniline N atom, and two chlorido ligands. The packing features N-H center dot center dot center dot O, N-H center dot center dot center dot Cl, C-H center dot center dot center dot Cl hydrogen bonding.