trans-diaqua{5,5 '-[(E,E)-pyridine-2,6-diylbis(methylidynenitrilo)]bis[pyrimidine-2,4(1H,3H)-dione]}zinc(II) nitrate hexafluorophosphate trihydrate

Özdemir, Namık; Dincer, M.; Doganer, G.; Astley, D.; Astley, S.

doi:10.1107/s0108270107008633

trans-diaqua{5,5 '-[(E,E)-pyridine-2,6-diylbis(methylidynenitrilo)]bis[pyrimidine-2,4(1H,3H)-dione]}zinc(II) nitrate hexafluorophosphate trihydrate

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Özdemir N., Dincer M., Doganer G., Astley D., Astley S. T.

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, vol.63, 2007 (SCI-Expanded)

Publication Type: Article / Article
Volume: 63
Publication Date: 2007
Doi Number: 10.1107/s0108270107008633
Journal Name: ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Ondokuz Mayıs University Affiliated: Yes

Abstract

The title compound, [Zn(C15H11N7O4)(H2O)(2)](NO3)(PF6)center dot 3H(2)O, contains a mononuclear zinc(II) complex. The Zn2+ centre is seven-coordinated in a slightly distorted pentagonal-bipyramidal geometry, with the two water O atoms located in the apical positions, and the pyridine N atom, the two imine N atoms and two carbonyl O atoms of the uracil groups located in the equatorial plane. The charge is balanced by PF6- and NO3- anions.