Determination of manganese, copper, cadmium and lead by FAAS after solid-phase extraction of their phenylpiperazine dithiocarbamate complexes on activated carbon

Cesur H.

TURKISH JOURNAL OF CHEMISTRY, cilt.27, sa.3, ss.307-314, 2003 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 27 Sayı: 3
  • Basım Tarihi: 2003
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.307-314
  • Anahtar Kelimeler: solid-phase extraction, phenylpiperazine dithiocarbamate, manganese, copper, cadmium, lead, flame atomic absorption spectrometry, activated carbon, ATOMIC-ABSORPTION SPECTROMETRY, BROMIDE-NAPHTHALENE ADSORBENT, MICROCRYSTALLINE NAPHTHALENE, EMISSION-SPECTROMETRY, WATER SAMPLES, TRACE AMOUNTS, STANDARD ALLOYS, PRECONCENTRATION, NICKEL, MORPHOLINE-4-CARBODITHIOATES
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

A solid-phase extraction method was developed for the pre-concentration of manganese, copper, cadmium and lead in water samples prior to their determination by flame atomic absorption spectrometry using phenylpiperazine dithiocarbamate as a new reagent. The optimum pre-concentration conditions have been investigated such as pH, volume of sample solution and the effects of some matrix elements. The obtained recovery was nearly 90 to 100, while the enrichment factor was 400 for metal spiked solutions.