A theoretical application of 3D J-resolved NMR spectroscopy for ISnKm (I=1/2, S=1/2 and 1, K=3/2) spin systems

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Saka I., Tezel O., Gencten A.

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, vol.58, no.2-3, pp.139-143, 2003 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 58 Issue: 2-3
  • Publication Date: 2003
  • Doi Number: 10.1515/zna-2003-2-311
  • Journal Name: ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.139-143
  • Keywords: product operator, 3D J-resolved NMR, spin-3/2, PRODUCT OPERATOR DESCRIPTION, PULSE EXPERIMENTS, FORMALISM, NUCLEI
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

In 3D J-resolved NMR spectroscopy, the chemical shift along one axis and the spin-spin coupling parameters along the two other different axes are resolved. Product operator theory is used for the analytical description of multi-dimensional NMR experiments on weakly coupled spin systems. In this study, the product operator description of heteronuclear 3D J-resolved NMR spectroscopy of weakly coupled ISn K-m (I = 1/2, S = 1/2 and 1, K = 3/2) spin systems is presented.