1-[(E)-(2-Phenoxyanilino)methylene]naphthalen-2(1H)-one
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, cilt.66, 2010 (SCI-Expanded)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 66
- Basım Tarihi: 2010
- Doi Numarası: 10.1107/s1600536810013851
- Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
- Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
- Ondokuz Mayıs Üniversitesi Adresli: Evet
Özet
The molecule of the title compound, C(23)H(17)NO(2), a Schiff base derived from 2-hydroxy-1-naphthaldehyde, crystallizes in the keto-amine tautomeric form. The dihedral angle between the aniline and hydroxybenzene rings is 77.41 (17)degrees , whereas the planes of the naphthaldehyde and fused aniline benzene rings are nearly coplanar, making a dihedral angle of 8.29 (15)degrees. Intramolecular N-H center dot center dot center dot O hydrogen bonding, a characteristic hydrogen bond for Schiff bases, helps to stabilize the molecular structure. Weak intermolecular C-H center dot center dot center dot pi interactions are present in the crystal structure.