A Novel Reaction of alpha-Carbonyl Oxime and Amido Alcohol: Synthesis, Characterization, Crystal Structure, and Thermal Studies of an Amido Alcohol, a New Oximino Alcohol Ligand, and its Metal Complexes

Kaya Y., Irez G., MUTLU GENÇKAL H., Buyukgungor O.

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, vol.41, no.7, pp.754-762, 2011 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 41 Issue: 7
  • Publication Date: 2011
  • Doi Number: 10.1080/15533174.2011.591300
  • Journal Name: SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Index Chemicus (IC)
  • Page Numbers: pp.754-762
  • Keywords: amido alcohol, oximino alcohol, reduction, SCHIFF-BASE LIGANDS, CU(II), COPPER(II), CO(II), NI(II), NICKEL(II), COBALT(II), ZINC(II), DIOXIME
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

In this study, a novel reaction was observed between isonitrosoacetophenone and 1-phenylethanol amine. Acetophenone was used as a starting material to synthesize isonitrosoacetophenone by reaction of acetophenone with n-butyl nitrite in the presence of sodium ethoxide and to synthesize 1-phenylethanol amine by reduction of isonitrosoacetophenone with LiAlH4 in diethyl ether. When the isonitrosoacetophenone reacted with 1-phenylethanol amine, (3E)-3-aza-5-(hydroxyimino)1,4-diphenylpent-3-en-1-ol monohydrate, a new oximino alcohol ligand and amido alcohol were obtained as associated product interestingly. Four complexes were prepared by treatment of oximino alcohol with metal salts such as Cu-II, Ni-II, Zn-II, and Co-II. Amido alcohol was characterized by single-crystal x-ray diffraction, and all complexes were characterized by using spectroscopic techniques and thermogravimetric analysis (TGA).