One- and two-dimensional heteropolynuclear complexes with tetracyanonickelate(II) and 2-pyridinemethanol

Sayin E., KÜRKÇÜOĞLU G. S., YEŞİLEL O. Z., Hokelek T., Buyukgungor O.

ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS, vol.229, no.8, pp.563-572, 2014 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 229 Issue: 8
  • Publication Date: 2014
  • Doi Number: 10.1515/zkri-2014-1756
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.563-572
  • Keywords: cyanide complexes, 2-pyridinemethanol complexes, tetracyanonickelate(II) complexes, C-H center dot center dot center dot Ni interaction, Ni center dot center dot center dot pi interaction, pi...pi interaction, O-H center dot center dot center dot O interaction, HYDROGEN-BONDS, COORDINATION POLYMERS, CRYSTAL-STRUCTURES, C-H, MAGNETIC-PROPERTIES, 1-ETHYLIMIDAZOLE, ZN(II)
  • Ondokuz Mayıs University Affiliated: Yes


Three new cyano complexes, [Cu(hmp)(2)] [Cu(hmpH)(2)Ni(mu-CN)(2)(CN)(2)](2)center dot 4H(2)O (1), [Zn-3(hmp)(2)(hmpH)(4) Ni-2(mu-CN)(6)(CN)(2)]center dot 2H(2)O (2) and [Cd-2(H2O)(2)(hmpH)(2)Ni(mu-CN)(4)Ni(mu-CN)(2)(CN)(2)] (3) (2-pyridinemethanol abbreviated to hmpH), have been synthesized and characterized by elemental analysis, vibrational spectroscopy (FT-IR and Raman), thermal and single-crystal X-ray diffraction analyses. In 1, Cu(II) ions are connected by the tetracyanonickelate(II) anions to form one-dimensional (1D) zig-zag chains. In 2, tetracyanonickelate(II) ions are coordinated to the neighboring three Zn(II) ions to form a one-dimensional double chain structure. In 3, Cd(II) ions are connected by tetrakis-monodentate tetracyanonickelate(II) ions to form a one-dimensional ladder-like chain. Adjacent ladder-like chains are linked by the bis-monodentate tetracyanonickelate(II) ions to generate a 2D network. The 3D supramolecular network of the complexes constructed by intermolecular interactions such as Ni center dot center dot center dot pi, C-H center dot center dot center dot Ni, pi...pi and hydrogen bonding interactions.