Synthesis, characterization, and crystal structure of bis[4-(3′-benzoyl)thiocarbamidophenyl]ether

AYDIN F., Aykaç D., Burcu Arslan N., Kazak C.

Crystallography Reports, vol.59, no.7, pp.955-960, 2014 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 59 Issue: 7
  • Publication Date: 2014
  • Doi Number: 10.1134/s1063774514070050
  • Journal Name: Crystallography Reports
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.955-960
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

The title compound, bis[4-(3′-benzoyl)thiocarbamidophenyl]ether, was synthesized by the reaction of benzoylisothiocyanate with 4,4′-diaminodiphenylether in aprotic solvent. The structure was determinated by means of elemental analysis and FT-IR, 1H-NMR, 13C-NMR and MS spectroscopic techniques. The crystal structure was characterized by X-ray syngle crystal analysis: orthorhombic, sp. gr. Pnna, Z = 4. In crystal packing, there are intramolecular hydrogen bond N-H⋯O generating S(6) motif, and intermolecular hydrogen bond N-H⋯S forming R2 2 (8) ring.