TURKISH JOURNAL OF CHEMISTRY, vol.43, no.6, pp.1622-1641, 2019 (SCI-Expanded)
Article / Article
TURKISH JOURNAL OF CHEMISTRY
Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
Ionic palladium complex, N-heterocyclic carbene, C-C bond formation, anionic palladium species, Suzuki-Miyaura cross-coupling reactions, CROSS-COUPLING REACTIONS, SUZUKI-MIYAURA, PHENYLBORONIC ACID, ARYL CHLORIDES, WATER, LIGANDS, BULKY, PD
Ondokuz Mayıs University Affiliated:
The synthesis of 3 benzimidazole-based ionic Pd(II)-NHC complexes (NHC: N-heterocyclic carbene) is presented. The structures of the complexes are as follows: [NHC-PdBr3](-) [NHC](+). The ionic palladium(II)-NHC complexes were synthesized in high yields and were fully characterized by nuclear magnetic resonance spectroscopy, X-ray diffraction, LC-MS/MS, and elemental analysis. These complexes have been identified as active catalysts in Suzuki-Miyaura reactions in a solution of 2-propanol and water at room temperature for different aryl bromides.