Synthesis and characterization of novel phthalocyanines containing N-(n-octyl)mercapto acetamide substituents

Akdemir N., Gumrukcuoglu I., Agar E.

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, vol.35, no.10, pp.819-824, 2005 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 35 Issue: 10
  • Publication Date: 2005
  • Doi Number: 10.1080/15533170500360297
  • Journal Name: SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Index Chemicus (IC)
  • Page Numbers: pp.819-824
  • Keywords: phthalocyanines, N-(n-octyl)-mercaptoacetamide group, synthesis, phthalonitrile, AGGREGATION PROPERTIES, COPPER PHTHALOCYANINE, METAL-FREE, METALLOPHTHALOCYANINES, AMIDE, MACROCYCLES, DERIVATIVES, IONOPHORES, COMPLEXES, POLYMERS
  • Ondokuz Mayıs University Affiliated: No

Abstract

Metal-free and metallo-phthalocyanines (M = Cu, Ni, Co, Zn) carrying four N-(n-octyl)mercapto acetamide group on peripheral positions have been synthesized from the corresponding phthalonitrile derivatives in the presence or the absence of anhydrous metal salt (CuCl, NiCl2 , CoCl2 , Zn(CH3COO)(2)). The novel compounds have been characterized by elemental analyses, IR, NMR, and UV/VIS spectroscopy.