Synthesis of Eight New Substituted Phenylamino and Diaminoglyoximes and Their Complexes with Some Transition Metals

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Macit M., Bati B.

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, vol.25, no.10, pp.1733-1747, 1995 (Scopus)

• Publication Type: Article / Article
• Volume: 25 Issue: 10
• Publication Date: 1995
• Doi Number: 10.1080/15533179508014695
• Journal Name: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
• Journal Indexes: Scopus
• Page Numbers: pp.1733-1747
• Ondokuz Mayıs University Affiliated: Yes

Abstract

Eight new substituted phenylamino and diaminoglyoximes; N-(3-methylphenyl)aminoglyoxime (MPAGH2), N-(2,6-dimethylphenyl)amino-glyoxime (DMPAGH2), N-(2-chloro-4-methylphenyl)aminoglyoxime (CMPAGH2), N-(2,4-dichlorophenyl)aminoglyoxime (DCPAGH2), N,N’-bis-(3-methylphenyl)diaminoglyoxime (BMPAGH2), N,N’-bis(2,6-dimethyl-phenyl)diaminoglyoxime (BDMPAGH2), N,N’-bis-(2-chloro-4-methyl-phenyl)diaminoglyoxime (BCMPAGH2), and N,N’-bis(2,4-dichlorophenyl)-diaminoglyoxime (BDCPAGH2) have been synthesized by the reactions of anti-chloroglyoxime and dichloroglyoxime with substituted aromatic amines in absolute ethanol. All these dioximes are in the anti- form according to IR and 1H NMR spectral data. The Ni(II), Cu(II) and Co(II) complexes of eight vic-dioximes have been prepared and their structures have been determined by using IR and UV-VIS spectral data and elemental analyses. © 1995, Taylor & Francis Group, LLC. All rights reserved.