Crystal structure and Hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](N,N,N ',N '-tetramethylethane-1,2-diamine)mercury(II)

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Qadir A. M., Kansiz S., DEGE N., Saif E.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.77, ss.1126-1133, 2021 (ESCI) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 77
  • Basım Tarihi: 2021
  • Doi Numarası: 10.1107/s2056989021010549
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
  • Sayfa Sayıları: ss.1126-1133
  • Anahtar Kelimeler: crystal structure, xanthate, mercury(II), Hirshfeld surface analysis, COMPLEXES, MERCURY, CADMIUM
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

The title four-coordinate mononuclear complex, [Hg(C3H5OS2)(2)(C6H16N2)] or [Hg(C3H5OS2)(2)(tmeda)] (tmeda: N,N,N',N'-tetramethylethane-1,2-diamine), has a distorted tetrahedral geometry. The HgII ion is coordinated to two N atoms of the N,N,N',N'-tetramethylethylenediamine ligand and two S atoms from two ethylxanthate xanthate ligands. In the crystal, molecules are linked by weak C-H center dot center dot center dot S hydrogen bonds, forming a two-dimensional supramolecular architecture in the ab plane. The most important contributions for the crystal packing are from H center dot center dot center dot H (59.3%), S center dot center dot center dot H (27.4%) and O center dot center dot center dot H (7.5%) interactions.