Crystal structure and Hirshfeld surface analysis of bis[(ethoxymethanethioyl)sulfanido](N,N,N ',N '-tetramethylethane-1,2-diamine)mercury(II)
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.77, ss.1126-1133, 2021 (ESCI, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 77
- Basım Tarihi: 2021
- Doi Numarası: 10.1107/s2056989021010549
- Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
- Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
- Sayfa Sayıları: ss.1126-1133
- Anahtar Kelimeler: crystal structure, xanthate, mercury(II), Hirshfeld surface analysis, COMPLEXES, MERCURY, CADMIUM
- Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
- Ondokuz Mayıs Üniversitesi Adresli: Evet
Özet
The title four-coordinate mononuclear complex, [Hg(C3H5OS2)(2)(C6H16N2)] or [Hg(C3H5OS2)(2)(tmeda)] (tmeda: N,N,N',N'-tetramethylethane-1,2-diamine), has a distorted tetrahedral geometry. The HgII ion is coordinated to two N atoms of the N,N,N',N'-tetramethylethylenediamine ligand and two S atoms from two ethylxanthate xanthate ligands. In the crystal, molecules are linked by weak C-H center dot center dot center dot S hydrogen bonds, forming a two-dimensional supramolecular architecture in the ab plane. The most important contributions for the crystal packing are from H center dot center dot center dot H (59.3%), S center dot center dot center dot H (27.4%) and O center dot center dot center dot H (7.5%) interactions.