Crystal structure and Hirshfeld surface analysis of 2-{[(4-iodophenyl)imino]methyl}-4-nitrophenol

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Faizi M. S. H., Alagoz T., Ahmed R., Cinar E. B., Ağar E., DEGE N., ...Daha Fazla

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.76, ss.1146-1153, 2020 (ESCI) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 76
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1107/s2056989020008191
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
  • Sayfa Sayıları: ss.1146-1153
  • Anahtar Kelimeler: crystal structure, salicylaldehyde derivative, 4-iodoan dine, 2-hydroxy-5-nitrobenzaldehyde, hydrogen bonding, PROTON-TRANSFER, SCHIFF-BASES, SOLID-STATE
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

The title compound, C13H9IN2O3, was synthesized by a condensation reaction between 2-hydroxy-5-nitrobenzaldehyde and 4-iodoaniline, and crystallizes in the orthorhombic space group Pna2(1). The 4-iodobenzene ring is inclined to the phenol ring by a dihedral angle of 39.1 (2)degrees. The configuration about the C=N double bond is E. The crystal structure features C-H center dot center dot center dot O hydrogen-bonding interactions. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the packing arrangement are O center dot center dot center dot H/H center dot center dot center dot O (26.9%) and H center dot center dot center dot H (22.0%) interactions.