Synthesis, crystal structure, spectroscopic and thermal properties of a novel mixed ligand copper(II) complex with 5,5-dimethylhydantoin and benzylamine

Taş M., Soylu S., Bati H.

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, vol.61, no.2, pp.133-138, 2006 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 61 Issue: 2
  • Publication Date: 2006
  • Journal Name: ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.133-138
  • Keywords: hydantoins, hydantoinato, 5,5-dimethylhydantoin, mixed ligand complex, thermal analyses, COORDINATION GEOMETRY
  • Ondokuz Mayıs University Affiliated: No

Abstract

The crystal structure of the newly synthesized complex, trans-aqua-bis(benzylamino)-bis(5,5-dimethylhydantoinato) copper(II) was determined by X-Ray single crystal data. The thermal analyses, FT-IR and magnetic susceptibility data are also presented. The complex crystallizes in the monoclinic system, space group C2. The complex features a distorted square pyramidal [CuN4O] coordination with 5,5-dimethylhydantoinato, benzylamine and water ligands. The 5,5-dimethylhydantoinato anion is bonded to the copper(II) ion via its deprotonated N atom in the 3-position.