JOURNAL OF COORDINATION CHEMISTRY, vol.69, no.9, pp.1463-1472, 2016 (SCI-Expanded)
Article / Article
JOURNAL OF COORDINATION CHEMISTRY
Science Citation Index Expanded (SCI-EXPANDED), Scopus
Chiral bicyclic N-heterocyclic carbene, expanded ring N-heterocyclic carbene, PEPPSI-type palladium complex, camphoric acid, X-ray diffraction, RHODIUM COMPLEXES, CATALYSTS
Ondokuz Mayıs University Affiliated:
Eight bicyclic amidinium precursors (3), prepared from R,S-tmcp (R,S-tmcp: (1R,3S)-diamino-1,2,2-trimethylcyclopentane) were described. Only five of the precursors (3a-e) could be converted to palladium complexes, (PdX2(6,7-NHC)PEPPSI) (4) by treatment with PdCl2, K2CO3, and pyridine (additional KBr was used for (PdBr2(6,7-NHC)PEPPSI)). The salts and complexes were fully characterized by spectroscopic methods and X-ray crystallography.