Diazidobis(propane-1,3-diamine)copper(II)

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Khan I. U., Ejaz E., Sahin O., Buyukgungor O.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, vol.66, 2010 (SCI-Expanded)

• Publication Type: Article / Article
• Volume: 66
• Publication Date: 2010
• Doi Number: 10.1107/s1600536810010184
• Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED)
• Ondokuz Mayıs University Affiliated: Yes

Abstract

In the title complex, [Cu(N(3))(2)(C(3)H(10)N(2))(2)], the Cu(II) ion resides on a centre of symmetry and is in a Jahn-Teller distorted octahedral coordination environment comprising two N atoms from azide anions in axial positions and four N atoms from propane-1,3-diamine (tn) ligands in equatorial positions. Intermolecular N-H center dot center dot center dot N hydrogen bonds produce R(2)(1)(6), R(2)(2)(8), R(2)(2)(12) and R(4)(2)(8) rings, generating a two-dimensional layer.