A Photoluminescent Polymeric 2D Silver(I) Complex Exhibits a Fishbone-like 1D Silver Cluster and New Coordination Mode of the Pyridine-2,3-Dicarboxylate

ÇOLAK A. T., Pamuk G., Uzun N., YEŞİLEL O. Z., SEMERCİ F., Gunay H., ...More

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, vol.23, no.2, pp.418-423, 2013 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 23 Issue: 2
  • Publication Date: 2013
  • Doi Number: 10.1007/s10904-012-9798-1
  • Journal Name: JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.418-423
  • Keywords: Pyridine-2,3-dicarboxylate complex, Silver(I) complex, Silver cluster, Photoluminescent silver complex, METAL-ORGANIC FRAMEWORKS, CRYSTAL-STRUCTURE, ARCHITECTURES, COPPER(I), NETWORKS, LIGANDS, ACID
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

In this study, a novel organic-inorganic hybrid compound with AgNO3 and 2,3-pyridinedicarboxylic acid (H(2)pydc), [Ag-2(mu(6)-pydc)](n) (1) has been synthesized. The molecular structure of complex has been determined by the single crystal X-ray diffraction. The complex has been observed to crystallize in the monoclinic space group P2(1)/c. The asymmetric unit of compound consists of two crystallographically different Ag(I) centers and one pydc ligand. The Ag1 and Ag2 adopt tetrahedral and T-shaped geometries, respectively. At the same time, the silver(I) compound consists of a fish bone similar to the 1D silver cluster. Furthermore, novel coordination mode shown by H(2)pydc indicates that the crystal exhibits photoluminescence in the solid state at room temperature.