(Z)-ethyl 4-chloro-2-[2-(2-methoxyphenyl)-hydrazono]-3-oxobutanoate

Alpaslan, G; Ozdamar, O; Odabasoglu, M; Ersanli, CC; Erdonmez, A; Iskeleli, NO

doi:10.1107/s1600536805030163

(Z)-ethyl 4-chloro-2-[2-(2-methoxyphenyl)-hydrazono]-3-oxobutanoate

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Alpaslan G., Ozdamar O., Odabasoglu M., Ersanli C., Erdonmez A., Iskeleli N.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, vol.61, 2005 (SCI-Expanded)

Publication Type: Article / Article
Volume: 61
Publication Date: 2005
Doi Number: 10.1107/s1600536805030163
Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED)
Ondokuz Mayıs University Affiliated: No

Abstract

The title compound, C13H15ClN2O4, adopts a keto-hydrazo tautomeric form stabilized by intramolecular N-H center dot center dot center dot O hydrogen bonds. The phenylhydrazone fragment is planar within +/- 0.028 (2) angstrom. The dihedral angle between the phenylhydrazone and oxobutanoate planes is 8.15 (9)degrees. Symmetry-related molecules are linked via C-H center dot center dot center dot O hydrogen bonds to form chains along [101].