Synthesis, spectra, thermal analysis and crystal structure of a mononuclear oxalato-copper(II) complex with monoethanolamine, [Cu(mea)(2)(ox)]

YILMAZ V. T., Senel E., Thone C.

JOURNAL OF COORDINATION CHEMISTRY, vol.56, no.16, pp.1417-1423, 2003 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 56 Issue: 16
  • Publication Date: 2003
  • Doi Number: 10.1080/00958970310001642582
  • Journal Name: JOURNAL OF COORDINATION CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1417-1423
  • Keywords: copper(II), oxalato, monoethanolamine, X-ray structure, MAGNETIC-PROPERTIES, OXALATE, MN, PHASE, OX, CU
  • Ondokuz Mayıs University Affiliated: No

Abstract

cis-bis(Monoethanolamine)oxalatocopper(II), cis-[Cu(mea)2(ox)], has been prepared and characterized by elemental analyses, IR, UV-Vis, thermal analysis and single crystal X-ray diffraction. The title complex crystallizes in the triclinic form with P (1) over bar space group. The copper(II) ion lies on a center of symmetry and is octahedrally coordinated by two bidentate neutral mea (N,O) and one bidentate ox (0,O') ligands. The individual molecules are held together by an extensive three-dimensional network of O-(HO)-O-..., N-(HO)-O-... and C-(HO)-O-... type intermolecular hydrogen bonds. The IR spectrum and thermal decomposition of the title complex are described.