Synthesis and spectral characterization of metal complexes of 1-(2-hydroxy-4-methylphenylazo)-2-naphthol

Kocaokutgen, H; Erdem, E

doi:10.1081/sim-200030245

Synthesis and spectral characterization of metal complexes of 1-(2-hydroxy-4-methylphenylazo)-2-naphthol

Kocaokutgen H., Erdem E.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, cilt.34, sa.10, ss.1843-1853, 2004 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 34 Sayı: 10
Basım Tarihi: 2004
Doi Numarası: 10.1081/sim-200030245
Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Index Chemicus (IC)
Sayfa Sayıları: ss.1843-1853
Anahtar Kelimeler: o,o '-dihydroxyazo dye, photoconductors, metal complexes, CHROMIUM COMPLEXES, DYES, NYLON, WOOL
Ondokuz Mayıs Üniversitesi Adresli: Hayır

Özet

The o,o'-dihydroxyazo dye, 1-(2-hydroxy-4-methylphenylazo)-2-naphthol (HMPAN), and its metal complexes (chromium, cobalt, and iron) having the ligand to metal ratio 2: 1 have been synthesized, but manganese forms a 1: 1 complex. The spectral characterization of HMPAN and its complexes by IR, UV-VIS, H-1 and C-13 NMR spectroscopic techniques, and elemental analyses are reported.