Synthesis, characterization and catalytic activity of Pd( II) complexes with N-allyl functionalized imidazol-2-ylidenes in Suzuki-Miyaura reaction
APPLIED ORGANOMETALLIC CHEMISTRY, cilt.28, sa.5, ss.324-331, 2014 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 28 Sayı: 5
- Basım Tarihi: 2014
- Doi Numarası: 10.1002/aoc.3128
- Dergi Adı: APPLIED ORGANOMETALLIC CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.324-331
- Anahtar Kelimeler: N-heterocyclic carbene, palladium, palladacyclic, crystal structure, Suzuki-Miyaura reaction, HETEROCYCLIC CARBENE LIGAND, PALLADIUM COMPLEXES, STEREODIRECTING LIGANDS, EFFICIENT CATALYSTS, CRYSTAL-STRUCTURES, COORDINATION, DEPROTECTION, MONONUCLEAR, NHC
- Ondokuz Mayıs Üniversitesi Adresli: Evet
Özet
A series of Pd-N-heterocyclic carbene (Pd-NHC) complexes were synthesized and characterized by elemental analysis and spectroscopic methods. In addition, the molecular structures of 3c and 4c were determined by X-ray diffraction studies. Finally, the performance of complexes 3 and 5 were studied on Suzuki-Miyaura reactions of phenylboronic acid with aryl bromides. Copyright (c) 2014 John Wiley & Sons, Ltd.