Synthesis, characterization and catalytic activity of Pd( II) complexes with N-allyl functionalized imidazol-2-ylidenes in Suzuki-Miyaura reaction

Gumusada R., Özdemir N., Gunay M. E., Dincer M., SOYLU M. S., Cetinkaya B.

APPLIED ORGANOMETALLIC CHEMISTRY, vol.28, no.5, pp.324-331, 2014 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 28 Issue: 5
  • Publication Date: 2014
  • Doi Number: 10.1002/aoc.3128
  • Journal Name: APPLIED ORGANOMETALLIC CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.324-331
  • Keywords: N-heterocyclic carbene, palladium, palladacyclic, crystal structure, Suzuki-Miyaura reaction, HETEROCYCLIC CARBENE LIGAND, PALLADIUM COMPLEXES, STEREODIRECTING LIGANDS, EFFICIENT CATALYSTS, CRYSTAL-STRUCTURES, COORDINATION, DEPROTECTION, MONONUCLEAR, NHC
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

A series of Pd-N-heterocyclic carbene (Pd-NHC) complexes were synthesized and characterized by elemental analysis and spectroscopic methods. In addition, the molecular structures of 3c and 4c were determined by X-ray diffraction studies. Finally, the performance of complexes 3 and 5 were studied on Suzuki-Miyaura reactions of phenylboronic acid with aryl bromides. Copyright (c) 2014 John Wiley & Sons, Ltd.