Synthesis, characterization and catalytic activity of Pd( II) complexes with N-allyl functionalized imidazol-2-ylidenes in Suzuki-Miyaura reaction

Gumusada R., Özdemir N., Gunay M. E., Dincer M., SOYLU M. S., Cetinkaya B.

APPLIED ORGANOMETALLIC CHEMISTRY, cilt.28, sa.5, ss.324-331, 2014 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 28 Sayı: 5
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1002/aoc.3128
  • Dergi Adı: APPLIED ORGANOMETALLIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.324-331
  • Anahtar Kelimeler: N-heterocyclic carbene, palladium, palladacyclic, crystal structure, Suzuki-Miyaura reaction, HETEROCYCLIC CARBENE LIGAND, PALLADIUM COMPLEXES, STEREODIRECTING LIGANDS, EFFICIENT CATALYSTS, CRYSTAL-STRUCTURES, COORDINATION, DEPROTECTION, MONONUCLEAR, NHC
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

A series of Pd-N-heterocyclic carbene (Pd-NHC) complexes were synthesized and characterized by elemental analysis and spectroscopic methods. In addition, the molecular structures of 3c and 4c were determined by X-ray diffraction studies. Finally, the performance of complexes 3 and 5 were studied on Suzuki-Miyaura reactions of phenylboronic acid with aryl bromides. Copyright (c) 2014 John Wiley & Sons, Ltd.