Synthesis, IR Spectrum, Thermal Analysis, and Crystal Structure of the Cyano-bridged Heteronuclear Polymeric Complex: [Zn(teta)Ni(mu-CN)(2)(CN)(2)](n)


Kuerkcueoglu G. S., YEŞİLEL O. Z., Kavlak I., Bueyuekguengoer O.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, cilt.635, sa.1, ss.175-178, 2009 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 635 Sayı: 1
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1002/zaac.200800337
  • Dergi Adı: ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.175-178
  • Anahtar Kelimeler: Cyano-bridged complex, Tetracyanonickelate complex, Triethylenetetramine complex, TETRACYANONICKELATE(II), CADMIUM(II), BEHAVIOR, INCLUSION, MOLECULES, ZINC(II)
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

The heteronuclear polymeric complex. (Zn(teta)Ni(mu-CN)(2)(CN)(2)](n) (teta: triethylenetetramine). was synthesized and characterized by elementel analysis, FT-IR spectroscopy, thermal analysis and single crystal X-ray diffraction techniques. The complex crystallizes in the monoclinic system, space group P2(1)/c and in which the Zn-II ion exhibits a distorted octahedral coordination by one tetradentate teta ligand and two bridging cyano groups as a trans position, whereas the Ni-II ion has square planer coordination and is coordinated by four cyano ligands. The decomposition reaction takes places in the temperature range 30-600 degrees C in the static air atmosphere.