Synthesis, IR Spectrum, Thermal Analysis, and Crystal Structure of the Cyano-bridged Heteronuclear Polymeric Complex: [Zn(teta)Ni(mu-CN)(2)(CN)(2)](n)

Kuerkcueoglu G. S., YEŞİLEL O. Z., Kavlak I., Bueyuekguengoer O.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, vol.635, no.1, pp.175-178, 2009 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 635 Issue: 1
  • Publication Date: 2009
  • Doi Number: 10.1002/zaac.200800337
  • Journal Name: ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.175-178
  • Keywords: Cyano-bridged complex, Tetracyanonickelate complex, Triethylenetetramine complex, TETRACYANONICKELATE(II), CADMIUM(II), BEHAVIOR, INCLUSION, MOLECULES, ZINC(II)
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

The heteronuclear polymeric complex. (Zn(teta)Ni(mu-CN)(2)(CN)(2)](n) (teta: triethylenetetramine). was synthesized and characterized by elementel analysis, FT-IR spectroscopy, thermal analysis and single crystal X-ray diffraction techniques. The complex crystallizes in the monoclinic system, space group P2(1)/c and in which the Zn-II ion exhibits a distorted octahedral coordination by one tetradentate teta ligand and two bridging cyano groups as a trans position, whereas the Ni-II ion has square planer coordination and is coordinated by four cyano ligands. The decomposition reaction takes places in the temperature range 30-600 degrees C in the static air atmosphere.