Bis(acesulfamato)tetraaquacobalt(II)

Icbudak, Hasan; Bulut, A; Cetin, N; Kazak, C

doi:10.1107/s0108270104028574

Bis(acesulfamato)tetraaquacobalt(II)

Icbudak H., Bulut A., Cetin N., Kazak C.

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, cilt.61, 2005 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 61
Basım Tarihi: 2005
Doi Numarası: 10.1107/s0108270104028574
Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

The crystal structure of the first acesulfame - metal complex, namely tetraaquabis[6-methyl-1,2,3-oxathiazin-4(3H)-onato 2,2-dioxide-kappaN] cobalt(II), [Co(C4H4NO4S)(2)(H2O)(4)], is reported. The Co-II ion resides on a twofold axis and is coordinated by four aqua ligands defining the basal plane and by two monodentate acesulfamate ligands, via their ring N atoms, in the axial positions. Two intra- and three intermolecular hydrogen-bonding interactions stabilize the crystal structure and form an infinite three-dimensional lattice.