Syntheses, IR spectra, thermal properties and crystal structures of novel cyano-bridged polymeric complexes of zinc(II) and cadmium(II) with tetracyanoplatinate(II)

KARADAĞ A., Oenal I., ŞENOCAK A., Ucar I., Bulut A., Bueyukguengoer O.

POLYHEDRON, vol.27, no.1, pp.223-231, 2008 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 27 Issue: 1
  • Publication Date: 2008
  • Doi Number: 10.1016/j.poly.2007.09.016
  • Journal Name: POLYHEDRON
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.223-231
  • Keywords: tetracyanoplatinate(II), zinc, cadmium, N-(2-hydroxyethyl)-ethylenediamine, coordination polymers, BIMETALLIC COMPLEXES, MAGNETIC-PROPERTIES, COPPER(II), LIGAND, ACID
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

Two novel one-dimensional polymeric cyano-bridged platinum(II) complexes of N-(2-hydroxyethyl)-ethylenediamine (hydeten), [M-II(hydeten)Pt(CN)(2)(mu-CN)(2)](n) (M-II = Zn-II (1) and Cd-II (2)), were synthesized and characterized by physico-chemical methods (elemental analysis, IR spectroscopy and thermoanalytical measurements) and X-ray diffraction. Thermal behaviours of 1 and 2 were followed using TG and DTA (DSC) techniques. The ID chain structures of I and 2 were verified by X-ray diffraction studies. According to the positions of the bridging cyano groups, in complex I the polymeric chains are built up via the 2,2-CT type, while in complex 2 the polymeric chains are built up via the 2,2-TT type. (C) 2007 Elsevier Ltd. All rights reserved.