Bis[N-(2-hydroxyethyl)ethylenediamine-kappa N-3,N ',O]nickel(II) squarate monohydrate

Ucar, I; Bulut, A

doi:10.1107/s1600536805039036

Bis[N-(2-hydroxyethyl)ethylenediamine-kappa N-3,N ',O]nickel(II) squarate monohydrate

Ucar I., Bulut A.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.61, 2005 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 61
Basım Tarihi: 2005
Doi Numarası: 10.1107/s1600536805039036
Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
Ondokuz Mayıs Üniversitesi Adresli: Hayır

Özet

In the title compound, [Ni(C4H12N2O)(2)](C4O4)center dot H2O or [Ni(Hydet-en)(2)](Sq)center dot H2O, where Hydet-en is N-(2-hydroxy-ethyl) ethylenediamine and Sq is the squarate dianion, the Ni-II centre has a distorted octahedral coordination geometry comprising four amine N and two hydroxyl O atoms from two tridentate Hydet-en ligands. All the O atoms of the squarate ldianion are involved in N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonding.