Synthesis, crystallographic analysis and Hirshfeld surface analysis of 4-bromo-2-{[2-(5-bromo-2-nitrophenyl)hydrazin-1-ylidene]methyl}-5-fluorophenol

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Yaman M., Aydemir E., DEGE N., Ağar E., Iskenderov T. S.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, vol.74, pp.1628-1637, 2018 (ESCI) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 74
  • Publication Date: 2018
  • Doi Number: 10.1107/s2056989018014627
  • Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
  • Journal Indexes: Emerging Sources Citation Index (ESCI), Scopus
  • Page Numbers: pp.1628-1637
  • Keywords: crystal structure, Hirshfeld surface, Hydrazone, crystal structure, hydrogen bonding, 5-bromo-4-fluoro-2-hydroxybenzaldehyde, CRYSTAL-STRUCTURE, COORDINATION POLYMER
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

The title compound, C13H8Br2FN3O3, is nearly planar with a dihedral angle of 10.6 (4)degrees between the two benzene rings. Intramolecular N-H center dot center dot center dot O and O-H center dot center dot center dot N hydrogen bonds occur. In the crystal, the molecules are linked by weak C-H center dot center dot center dot O and C-H center dot center dot center dot Br hydrogen bonds. The roles of the intermolecular interactions in the crystal packing were clarified using Hirshfeld surface analysis.