Spectroscopy and X-ray studies of {{6,6'-dimethoxy-2,2'-[ethane-1,2-diyl-bis-(nitrilomethylidyne)]diphenolato}(aqua)-dioxouranium(VI)} dehydrate

Ataol C. Y., Senyuz N., Bat H.

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, cilt.40, sa.9, ss.671-675, 2014 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 40 Sayı: 9
  • Basım Tarihi: 2014
  • Doi Numarası: 10.1134/s1070328414090139
  • Dergi Adı: RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.671-675
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

The C18H20N2O7U center dot 2H(2)O (I) complex has been prepared and characterized by single crystal X-ray diffraction properties (CIF file CCDC no. 913243). The title compound crystallizes in the orthorhombic system, space group Pbca with a = 19.542(5), b = 9.916(5), c = 21.940(5) , V = 4252(3) (3) and Z = 8. In complex I, the U atom has a distorted pentagonal-bipyramidal geometry with a tetradentate Schiff base ligand and water molecule in the equatorial plane and oxo atoms in the axial positions. The crystal packing occurs intra-inter molecular hydrogen bonds.