Spectroscopy and X-ray studies of {{6,6'-dimethoxy-2,2'-[ethane-1,2-diyl-bis-(nitrilomethylidyne)]diphenolato}(aqua)-dioxouranium(VI)} dehydrate

---

Copy For Citation

Ataol C. Y., Senyuz N., Bat H.

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, vol.40, no.9, pp.671-675, 2014 (SCI-Expanded)

• Publication Type: Article / Article
• Volume: 40 Issue: 9
• Publication Date: 2014
• Doi Number: 10.1134/s1070328414090139
• Journal Name: RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Page Numbers: pp.671-675
• Ondokuz Mayıs University Affiliated: Yes

Abstract

The C18H20N2O7U center dot 2H(2)O (I) complex has been prepared and characterized by single crystal X-ray diffraction properties (CIF file CCDC no. 913243). The title compound crystallizes in the orthorhombic system, space group Pbca with a = 19.542(5), b = 9.916(5), c = 21.940(5) , V = 4252(3) (3) and Z = 8. In complex I, the U atom has a distorted pentagonal-bipyramidal geometry with a tetradentate Schiff base ligand and water molecule in the equatorial plane and oxo atoms in the axial positions. The crystal packing occurs intra-inter molecular hydrogen bonds.