Synthesis, spectral, thermal and structural characterization of mer-triaquaorotatoquinoxaline cadmium(II) dihydrate

YEŞİLEL O. Z., Pasaoglu H., Akdag K., Bueyuekguengoer O.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, vol.633, no.10, pp.1731-1734, 2007 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 633 Issue: 10
  • Publication Date: 2007
  • Doi Number: 10.1002/zaac.200700165
  • Journal Name: ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1731-1734
  • Keywords: cadmium, orotato complex, orotic acid, quinoxaline complex, OROTIC-ACID, CRYSTAL-STRUCTURES, MOLECULAR-STRUCTURE, HYDROTHERMAL SYNTHESIS, COPPER(II) COMPLEXES, COBALT(II), NICKEL(II), BEHAVIOR, AMINE, ZINC
  • Ondokuz Mayıs University Affiliated: No

Abstract

The new orotate complex of cadmium(11) with quinoxaline, mer-[Cd(HOr)(H2O)(3)(QX)]center dot 2H(2)O, was synthesized and characterized by elemental analysis, FT-IR spectroscopy, thermal analysis and single crystal X-ray diffraction techniques. The complex crystallizes in the triclinic system, space group P (1) over bar. The Cd2+ ion exhibits a distorted octahedral coordination by one bidentate orotate, one monodentate quinoxaline and three aqua ligands. The uncoordinated water molecules link the orotate, quidoxaline and