Trans-Bis(diethanoIamine)bis(isothiocyanato)nickel(II)

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YILMAZ V. T., KARADAĞ A., Thöne G., Herbst-lrmer R.

Acta Crystallographica Section C: Crystal Structure Communications, vol.56, no.8, pp.948-949, 2000 (SCI-Expanded)

• Publication Type: Article / Article
• Volume: 56 Issue: 8
• Publication Date: 2000
• Doi Number: 10.1107/s0108270100007289
• Journal Name: Acta Crystallographica Section C: Crystal Structure Communications
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Page Numbers: pp.948-949
• Ondokuz Mayıs University Affiliated: Yes

Abstract

In the neutral title complex, trans-bis(2,2′-iminodiethanolW,O)bis(isothiocyanato)nickel(II), [NiCNCS)2(C4H11NO2)2], the isothiocyanate ions and the diethanolamine molecules act as monodentate and bidentate ligands, respectively. The NiH ion exhibits a distorted octahedral configuration with crystallographically imposed inversion symmetry and NNCS-Ni-Namine and NNCS-Ni-Oamine bond angles of 88.78 (10) and 89.44 (10), respectively. The Ni-N bond distances are in the range 2.069 (3)-2.096 (2) Å. The molecules are linked by hydrogen bonds to form a three-dimensional infinite lattice. © 2000 International Union of Crystallography all rights reserved.