Synthesis, crystal structure, spectroscopic and thermal properties of a novel mixed ligand copper(II) complex with 5,5-dimethylhydantoin and benzylamine

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Taş M., Soylu S., Batı H.

Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, vol.61, no.2, pp.133-138, 2006 (SCI-Expanded)

• Publication Type: Article / Article
• Volume: 61 Issue: 2
• Publication Date: 2006
• Doi Number: 10.1515/znb-2006-0203
• Journal Name: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
• Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Page Numbers: pp.133-138
• Keywords: 5,5-Dimethylhydantoin, Hydantoinato, Hydantoins, Mixed Ligand Complex, Thermal Analyses
• Ondokuz Mayıs University Affiliated: Yes

Abstract

The crystal structure of the newly synthesized complex, trans-aqua-bis(benzylamino)-bis(5,5-dimethylhydantoinato) copper(II) was determined by X-Ray single crystal data. The thermal analyses, FT-IR and magnetic susceptibility data are also presented. The complex crystallizes in the monoclinic system, space group C2. The complex features a distorted square pyramidal [CuN4O] coordination with 5,5-dimethylhydantoinato, benzylamine and water ligands. The 5,5-dimethylhydantoinato anion is bonded to the copper(II) ion via its deprotonated N atom in the 3-position. © 2006 Verlag der Zeitschrift für Naturforschung.