(2,2 '-bipyridine)saccharinatosilver(I)
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, cilt.63, 2007 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 63
- Basım Tarihi: 2007
- Doi Numarası: 10.1107/s160053680705845x
- Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Ondokuz Mayıs Üniversitesi Adresli: Evet
Özet
The title complex, [Ag(C7H4NO3S)(C10H8N2)], has a mononuclear structure in which the Ag-I ion is coordinated by two N atoms from 2,2 '-bipyridine and one N atom from saccharinate, forming a distorted T-shaped (or trigonal-planar) AgN3 arrangement. The bite angle of bpy is 71.69 (6)degrees, which contributes significantly to the distortion of the coordination geometry. Molecules are connected by C-H center dot center dot center dot O and pi(bpy)-pi(bpy) interactions with a centroid-centroid separation of 3.6741 (13) angstrom.