A theoretical application of SEMUT NMR spectroscopy to deuterated compounds

Gençten A., Tezel Ö., Köroǧlu A.

Applied Magnetic Resonance, vol.20, no.1-2, pp.265-273, 2001 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 20 Issue: 1-2
  • Publication Date: 2001
  • Doi Number: 10.1007/bf03162325
  • Journal Name: Applied Magnetic Resonance
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.265-273
  • Ondokuz Mayıs University Affiliated: Yes

Abstract

The product operator formalism is widely used for analytical description of multiple-pulse nuclear magnetic resonance (NMR) experiments for weakly coupled spin systems. 13C subspectral editing with a multiple quantum trap (SEMUT) NMR spectroscopy is used for subspectral editing of CH3, CH2, CH and C groups. In this study, after obtaining the evolutions of IxSy2 and IySy2 product operators under the spin-spin coupling Hamiltonian for IS (I = 1/2, S = 1) spin system, the product operator technique was applied for the analytical description of 13C SEMUT NMR for CDn groups. Then, theoretical discussion and experimental suggestions for the subspectral editing of CD3, CD2, CD and C groups are presented. © Springer-Verlag 2001.