Synthesis, crystal structures and Hirshfeld surface analysis of 1,4-dibenzyl-6-methyl-1,4-dihydroquinoxaline-2,3-dione

Creative Commons License

Cinar E. B., Zouitini A., Rodi Y. K., Ouzidan Y., Marrot J., Prim D., ...Daha Fazla

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.76, ss.1361-1370, 2020 (ESCI) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 76
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1107/s2056989020009895
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
  • Sayfa Sayıları: ss.1361-1370
  • Anahtar Kelimeler: crystal structure, Hirshfeld surfaces, quinoxaline, hydrogen bonding, QUINOXALINE DERIVATIVES
  • Ondokuz Mayıs Üniversitesi Adresli: Evet

Özet

The title quinoxaline molecule, C23H20N2O2, is not planar, the dihedral angle angle between the mean planes of the benzene rings being 72.54 (15)degrees. In the crystal, molecules are connected into chains extending parallel to (10 (1) over bar) by weak C-H center dot center dot center dot O hydrogen bonds. Weak C-H center dot center dot center dot pi interactions link the chains, forming a three-dimensional network structure. Hirshfeld surface analysis revealed that the most important contributions for the crystal packing are from H center dot center dot center dot H (48.7%), H center dot center dot center dot C/C center dot center dot center dot H (32.0%), H center dot center dot center dot O/O center dot center dot center dot H (15.4%), C center dot center dot center dot C (1.9%), H center dot center dot center dot N/N center dot center dot center dot H (1.1%) contacts.