Crystal structure of {(E)-4-[(1-allyl-1H1,2,3-triazol-4-yl)methoxy] benzylidene}[2-(morpholin-4-yl) ethyl] amine
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, vol.70, 2014 (ESCI, Scopus)
- Publication Type: Article / Article
- Volume: 70
- Publication Date: 2014
- Doi Number: 10.1107/s1600536814016754
- Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
- Journal Indexes: Emerging Sources Citation Index (ESCI), Scopus
- Keywords: crystal structure, Schiff base, morpholine, 1,2,3-triazole, disorder
- Open Archive Collection: AVESIS Open Access Collection
- Ondokuz Mayıs University Affiliated: Yes
Abstract
In the title compound, C19H25N5O2, the morpholine ring has a chair conformation. The plane of the central benzene ring makes dihedral angles of 88.75 (12) and 60.02 (7)degrees, respectively, with the mean plane formed by the four planar C atoms of the morpholine ring and with the plane of the triazole ring. In the crystal, molecules are linked via C-H center dot center dot center dot pi interactions, forming slabs lying parallel to (10(1) over bar). The C atoms of the bridging ethylene group, between the morpholine and benzene rings, and the terminal ethene group of the prop-1ene substituent attached to the triazole ring, are disordered over two sets of sites, with an occupancy ratio of 0.634 (13): 0.366 (13).